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Kumagai, Yuta
Hoshasen Kagaku (Internet), (99), p.53 - 56, 2015/04
Radiation-induced degradation of 2-chlorophenol (2-ClPh) in zeolite/water mixtures was studied in order to consider a possibility of adsorption on zeolites to improve efficiencies of irradiation treatments of water contaminated by organic compounds. The degradation of 2-ClPh by -ray irradiation was investigated as a model compound. The degradation was evaluated by chloride ion (Cl) production. A high concentration of Cl was observed after the irradiation of a mixture with a mordenite-type zeolite (NaMOR), whereas A-type and X-type zeolites showed no significant effect. Therefore, for the mixture with NaMOR, effects of pH of the solution and of the 2-ClPh concentration were examined. At pH 5.7, the excess production of Cl was induced by the addition of NaMOR. Concurrently, adsorption of 2-ClPh on NaMOR was observed. When the mixture contained a higher concentration of 2-ClPh at pH 5.7, the Cl production increased. The adsorption of 2-ClPh also increased with increasing concentration. The results suggest that organics adsorbed on zeolites are decomposed by irradiation effectively at high adsorption concentrations.
Kimura, Atsushi; Taguchi, Mitsumasa; Otani, Yoshimi*; Takigami, Machiko; Shimada, Yoshitaka*; Kojima, Takuji; Hiratsuka, Hiroshi*; Namba, Hideki
Radiation Physics and Chemistry, 75(1), p.61 - 69, 2006/01
Times Cited Count:13 Percentile:65.83(Chemistry, Physical)Decomposition of -Nonylphenols (NPs) in water at 1 mol dm was decreased exponentially with absorbed dose when NPs were irradiated by Co-rays. Two products having molecular weight of 236, presumably OH adducts of NPs, were detected by LC-MS analyses. The elimination of estrogen activity of aqueous NPs solution including such irradiation products at 5000 Gy (J kg) was confirmed by the yeast two hybrid assay. These results should expand the application of ionizing radiation to the treatment of NPs.
Morioka, Atsuhiko; Sakurai, Shinji; Okuno, Koichi*; Tamai, Hiroshi
Purazuma, Kaku Yugo Gakkai-Shi, 81(9), p.645 - 646, 2005/09
A 300 C heat-resistant neutron shielding material is newly developed, which consists of phenol-based resin with 5 weight-% boron. The neutron shielding performance of the developed resin, examined by the Cf neutron source, is almost the same as that of the polyethylene. The resin is applicable to the port section of vacuum vessel of the DD plasma device to suppress the streaming neutrons and to reduce the nuclear heating of the superconducting coils.
X.Huang*; Arai, Hidehiko; Matsuhashi, Shimpei; Miyata, Teijiro
Chemistry Letters, 0(4), p.273 - 274, 1996/00
no abstracts in English
*; *; *; Terakawa, Akira*
Bulletin of the Chemical Society of Japan, 36(6), p.721 - 727, 1963/00
Times Cited Count:20no abstracts in English
Yamaguchi, Ichiro
Bulletin of the Chemical Society of Japan, 34(6), p.744 - 747, 1961/00
Times Cited Count:14no abstracts in English
Kumagai, Yuta
no journal, ,
no abstracts in English